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Author ORCID Identifier
https://orcid.org/0000-0002-9946-3923
AccessType
Open Access Dissertation
Document Type
dissertation
Degree Name
Doctor of Philosophy (PhD)
Degree Program
Polymer Science and Engineering
Year Degree Awarded
2022
Month Degree Awarded
September
First Advisor
Todd Emrick
Subject Categories
Polymer Chemistry
Abstract
This dissertation encompasses the synthesis, characterization and application of novel polymer zwitterions that significantly expand the library of available zwitterionic polymers. Their facile synthesis is facilitated by the preparation of a novel functional sultone precursor molecule, which can be ring-opened by commercially available phosphine, amine and sulfide nucleophiles, affording phosphonium, ammonium or sulfonium sulfonate monomers, respectively. Most notably, this work describes the invention of phosphonium-based polymer zwitterions, establishing a new class of zwitterionic polymer structures with unique solution and interfacial properties. Furthermore, the incorporation of these phosphonium sulfonates into block copolymer architectures with conventional polymer zwitterions, and the resulting switchable solution assemblies, are described. Additionally, this work compares the novel phosphonium and ammonium sulfonate polymers, elucidating key structure-property relationship information on the effect of the identity of the cation-bearing atom on material properties, such as solution behavior and surface activity. Finally, the novel sulfonium sulfonate polymers, compared to analogous, ix previously established sulfothetin polymer zwitterions, display significant differences in their solubility, surface activity and stability, which may be attributed to their respective strength of inter-zwitterion interactions.
DOI
https://doi.org/10.7275/31043730
Recommended Citation
Brown, Marcel U., "Expanding the Polymer Zwitterion Library – Novel Phosphonium-based Polymer Zwitterions and Analogous Structures" (2022). Doctoral Dissertations. 2598.
https://doi.org/10.7275/31043730
https://scholarworks.umass.edu/dissertations_2/2598