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Author ORCID Identifier

https://orcid.org/0000-0001-6956-3571

AccessType

Open Access Dissertation

Document Type

dissertation

Degree Name

Doctor of Philosophy (PhD)

Degree Program

Civil and Environmental Engineering

Year Degree Awarded

2022

Month Degree Awarded

September

First Advisor

Dr. Guoping Zhang

Second Advisor

Dr. Andrew Whittle

Third Advisor

Dr. C.S. Chang

Fourth Advisor

Dr. Shuang Zhou

Subject Categories

Geotechnical Engineering

Abstract

Clay minerals are a class of phyllosilicates as the major solid constituents in cohesive fine-grained soils (e.g., clays). Owing to their tiny size (i.e., < 2 μm), high aspect ratio, and active surface properties that inherit from the geological process, clay minerals can extensively interact with other suspended matter (e.g., exoployemers, microorganisms) and dissolved ions via the process of flocculation and aggregation, resulting in the formation of larger, porous cohesive particulate aggregates or flocs. Such a complex mechanism of microscale particle interaction generates significant challenges for understanding the bulk clay behavior as a particulate system. In order to better characterize the flocculation and aggregation of clay minerals under various stimuli and to understand the underlying mechanism of particle interactions, particle/aggregate size kinetics of flocculated suspensions of illite, a representative 2:1 clay mineral abundant in marine soils, are studied with varied ionic strength induced by monovalent salt (NaCl), pH, and hydrodynamic shearing in the first phase of this research. Furthermore, a new statistical data binning method termed “bin size index” (BSI) was employed to determine the probability density function (PDF) distributions of flocculated illite suspensions. The statistical results demonstrate that the size kinetics of flocculated illite suspensions is chiefly controlled by the face-to-face and edge-to-face interparticle interactions under the mutual effects of ionic strength and pH, while the hydrodynamic shearing has minimal effects on the variation of particle size groups. In the second phase of this research, the mechanics of clay aggregates are studied using an innovative measurement technique and analytical approach. Individual clay minerals prepared with different mineralogy and salinities are tested via unconfined compression, which shows that the increasing ionic strength can improve the strength and stiffness of clay aggregates, which are further affected by the mineralogical compositions and dominant microfabric in different water chemistry. In the final phase of this research, a collaborative study with an environmental engineer on an NSF CAREER project was conducted to investigate the mechanical behavior of macroscale, light-induced oxygenic granules (biofilm aggregates) using the same technique and analytics developed for the individual clay aggregates. The findings are expected to provide reference values to subsequent studies and engineering practices associated with the water treatment process.

DOI

https://doi.org/10.7275/30957909

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