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Author ORCID Identifier
Campus-Only Access for One (1) Year
Doctor of Philosophy (PhD)
Polymer Science and Engineering
Year Degree Awarded
Month Degree Awarded
Polymer and Organic Materials
By experimentally investigating the invasion of a polyelectrolyte into a charged hydrogel, we report a novel coacervate band formation deep inside the gel, unlike in equilibrated coacervate gel composites. The mobility and the position of this band are found to be controlled by the concentration gradient of the invasive species and the pH gradient within the gel matrix. Using turbidimetry, static and dynamic light scattering, and rheology, we have monitored the beginning location and time of birth of the coacervate band inside the gel and its time evolution. Once a band is born, with time, it becomes more intense and broadens downstream with the permanent localization of the initial beginning location. Even more remarkably, it forms daughter bands upstream at later stages of the band’s life, suggesting a backflow of the guest molecules. The various quantitative features of the band depend crucially on the initial concentration gradient of the invader. Our observations open a new direction in coacervate gel systems under non-equilibrium conditions.
Wang, Yu-Lin, "DYNAMICS OF POLYELECTROLYTE TRANSPORT IN OPPOSITELY CHARGED HYDROGELS" (2023). Doctoral Dissertations. 2866.
Available for download on Sunday, May 26, 2024