Irvine, William

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Job Title
Professor Emeritus of Astronomy
Last Name
Irvine
First Name
William
Discipline
Cosmology, Relativity, and Gravity
External Galaxies
Other Astrophysics and Astronomy
Physical Processes
Stars, Interstellar Medium and the Galaxy
The Sun and the Solar System
Expertise
Introduction
At present, in 2014, my principal activity in astrochemistry and astrobiology is as an editor of the Encyclopedia of Astrobiology, published by Springer.
I began my research career in astronomy with a dissertation in cosmology, specifically on the growth of structure in the expanding universe. A result was what has been called the Layzer-Irvine, or the Cosmic Energy, equation. A post-doctoral position at the Leiden Observatory in the Netherlands subsequently led me into those aspects of planetary and atmospheric science dealing with the transmission and reflection of radiation by atmospheres and rough surfaces, including what has been called the Hapke-Irvine law or relation.
After the establishment of the Five College Radio Astronomy Observatory, particularly the 14-meter diameter millimeter-wave telescope at the University of Massachusetts Amherst, my research switched into two new areas: the chemistry of dense interstellar clouds and the physics and chemistry of comets. Dense interstellar clouds are the most massive objects in the universe consisting of material subject to the chemical bond. The composition and the processes determining this composition are thus of fundamental importance to our understanding of the universe. As the chemical composition affects the heating and cooling processes of the cloud, there is a tight evolutionary link between chemistry, cloud physics and evolution, and star formation.
Although by far the most abundant molecular species in these clouds is molecular hydrogen, the trace constituents exhibit a complex organic (carbon-based) chemistry. At the least demonstrating that organic chemistry is widespread in the universe, this composition raises the question of what role interstellar organics might have played in the origin of life on Earth or elsewhere --- thus, this research becomes a part of astrobiology. An aspect of these studies is the search for and identification of new interstellar molecules. My colleagues and I have played a role in the discovery of some 13 such new molecular species, involving collaborations with astronomers
at Nobeyama Radio Observatory in Japan and the Onsala Space Observatory in Sweden.
The same radio techniques at millimeter and submillimeter wavelengths used to study interstellar matter are also useful in observing comets, the least processed material surviving from the origin of the solar system. Observations of cometary organic molecules can give information on cometary physics and the relation of comets to interstellar material. Since comets were clearly a source of organic matter for the early Earth, studying the nature and links between the organic chemistry in interstellar clouds and in comets is an important aspect of astrobiology.
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Now showing 1 - 10 of 105
  • Publication
    IDENTIFICATION OF THE INTERSTELLAR CYANOMETHYL RADICAL (CH2CN) IN THE MOLECULAR CLOUDS TMC-1 AND SAGITTARIUS-B2
    (1988) Irvine, William M.; FRIBERG, P; HJALMARSON, A; ISHIKAWA, S; KAIFU, N; KAWAGUCHI, K; MADDEN, SC; MATTHEWS, HE; OHISHI, M; SAITO, S; SUZUKI, H; THADDEUS, P; TURNER, BE; YAMAMOTO, S; ZIURYS, LM
    The authors report the astronomical identification of the cyanomethyl radical, CH2CN, the heaviest nonlinear molecular radical to be identified in interstellar clouds. The complex fine and hyperfine structures of the lowest rotational transitions at about 20.12 and 40.24 GHz are resolved in TMC-1, where the abundance appears to be about 5×10-9 relative to that of H2. In Sgr B2 the hyperfine structure is blended in the higher frequency transitions at 40, 80, and 100 GHz, although the spin-rotation doubling is clearly evident. Preliminary searches in other sources indicate that the distribution of CH2CN is similar to that for such carbon chain species as HC3N or C4H.
  • Publication
    HCN and HNC in comets C/2000 WM1 (Linear) and C/2002 C1 (Ikeya-Zhang)
    (2003-01-01) Irvine, William M.; Bergman, P; Lowe, TB; Matthews, H; McGonagle, D; Nummelin, A; Owen, T
    Comets have been suggested as a possibly significant source of organic molecules to the early Earth. Hydrogen cyanide (HCN) is important in models of prebiotic chemistry, but may be difficult to form in the early terrestrial environment, while hydrogen isocyanide (HNC) is a `classical' tracer of interstellar ion-molecule chemistry. We have observed both HCN and HNC in 2 recent comets, bringing the number of comets with published measurements of the HNC/HCN abundance ratio to 6. The HNC/HCN ratio in comet Ikeya-Zhang appears to increase with decreasing heliocentric distance, as was previously observed for comet Hale-Bopp, indicating that the HNC is produced at least in part by processes in the cometary coma (atmosphere) and is not simply a constituent of the nuclear ices. Both comets C/2000 WM1 (Linear) and C/2002 C1 (Ikeya-Zhang) exhibit values of the HNC/HCN ratio that appear to be too large (0.09–0.19) tobe matched by current models of coma chemistry. Cometary HNC maybe a photodissociation product of organic grains or large organic polymers stored in the nucleus. We have also set a limit on the emission from the NO radical in comet WM1.
  • Publication
    UPPER LIMITS FOR THE ETHYL-CYANIDE ABUNDANCES IN TMC-1 AND L134N - CHEMICAL IMPLICATIONS
    (1991) MINH, YC; Irvine, William M.
    We have sought interstellar ethyl-cyanide via its 202–101 transition towards two cold, dark clouds and report upper limits of the total column densities of 3×1012cm–2 and 2×1012cm–2 for TMC-1 and L134N, respectively. We also observed the 202–101 transition of vinyl cyanide previously identified in TMC-1 by Matthews and Sears (1983b). The detection of vinyl cyanide and the non-detection of ethyl cyanide in TMC-1 are consistent with gas phase ion-molecule chemical models, and there is thus no necessity of invoking grain surface synthesis for vinyl cyanide in cold clouds.
  • Publication
    RECENT OBSERVATIONS OF INTERSTELLAR-MOLECULES - DETECTION OF CCO AND A LIMIT ON H2C3O
    (1992) BROWN, RD; CRAGG, DM; GODFREY, PD; Irvine, William M.; MCGONAGLE, D; OHISHI, M
    In order to test gas-phase reaction schemes for the production of small oxides of carbon in cold, dense interstellar clouds, we have searched for the radical CCO and for propadienone (H2C3O) in Taurus Molecular Cloud 1, a nearby cloud which exhibits a rich organic chemistry. The radical CCO has been detected with a fractional abundance some two orders of magnitude less than that of CCS, about one order of magnitude less than that of H2CCO, and slightly less than that of C3O. An upper limit has been obtained on the abundance of propadienone which is slightly less than that of its isomer propynal (HC2CHO).
  • Publication
    MOLECULAR ABUNDANCE VARIATIONS AMONG AND WITHIN COLD, DARK MOLECULAR CLOUDS
    (1992) OHISHI, M; Irvine, William M.; KAIFU, N
  • Publication
    Observations of deuterated molecules with the large millimeter telescope
    (2002-01-01) Irvine, William M.; Schloerb, FP
    The characteristics of a new, very sensitive radio telescope currently under construction for use in the 1–4 mm wavelength region, the large millimeter telescope (LMT), are described. The LMT with its planned instrumentation will provide an important new tool for studies of deuterated molecules, giving astronomers powerful probes of the linked chemistry and physics of interstellar molecular clouds and comets.
  • Publication
    SCATTERING OF LIGHT BY STOCHASTICALLY ROUGH PARTICLES
    (1989) PELTONIEMI, JI; LUMME, K; MUINONEN, K; Irvine, William M.
    The single particle phase function and the linear polarization for large stochastically deformed spheres have been calculated by Monte Carlo simulation using the geometrical optics approximation. The radius vector of a particle is assumed to obey a bivariate lognormal distribution with three free parameters: mean radius, its standard deviation and the coherence length of the autocorrelation function. All reflections/refractions which include sufficient energy have been included. Real and imaginary parts of the refractive index can be varied without any restrictions. Results and comparisons with some earlier less general theories are presented. Applications of this theory to the photometric properties of atmosphereless bodies and interplanetary dust are discussed.
  • Publication
    ABUNDANCE AND CHEMISTRY OF INTERSTELLAR HOCO+
    (1991) MINH, YC; BREWER, MK; Irvine, William M.; FRIBERG, P; JOHANSSON, LEB
    Column densities of 10 to the 15th/sq cm toward the Galactic center and not more than 10 to the 12th/sq cm for cold dark clouds are derived from observations using an LVG model, and the chemical implications are discussed. The HOCO(+) 4(04)-3(03) line toward Sgr A is mapped. The fractional abundance of HOCO(+) in the Galactic center region was found to be three orders of magnitude larger than predicted by quiescent ion-molecule chemistry and an order of magnitude larger than predicted by an MHD shock model. It is suggested that the possibly high CO2 abundance, and consequently the observed HOCO(+) abundance in the Galactic center, may result from UV photolysis of grain mantles.
  • Publication
    Are clouds collapsing at the 2 ' north position of Sagittarius B2?
    (1998) Minh, YC; Haikala, L; Hjalmarson, A; Irvine, William M.
    The 3 mm lines of HCO+2 and HNCO have been observed toward Sgr B2. Besides the well-known "principal cloud" and an extended envelope, we find another gas cloud 2' north of Sgr B2(M). This 2' north (2' N) cloud which may be located behind the principal cloud, has a total mass of ~105 M and a diameter of ~7 pc. HCO+2 and HNCO exist mainly at 2' north, and their column densities are about 2.2 × 1014 and 2.3 × 1015 cm-2, respectively. The fractional abundances of these species relative to molecular hydrogen appear to be enhanced by at least a factor of 10 compared to the principal cloud. We have also identified redshifted and blueshifted high-velocity components which move toward the 2' N position with projected velocities of ±30 km s-1. These components are located symmetrically around 2' N, along the Galactic plane, and have diameters of about 4-5 pc and masses of ~1 × 104 M. The flow energies are large enough to initiate new star formation in the 2' N region on the free-fall timescale of 105 yr. This large-scale collapsing motion may cause a strong shock in the 2' N cloud and result in the enhancement of HCO+2 and HNCO.
  • Publication
    DETECTION OF FORMIC-ACID IN THE COLD, DARK CLOUD L134N
    (1990) Irvine, William M.; FRIBERG, P; KAIFU, N; MATTHEWS, HE; MINH, YC; OHISHI, M; ISHIKAWA, S
    The detection of formic acid (HCOOH) in a cold dark interstellar cloud (L134N) is reported. The observed abundance of 3 x 10 to the 10th relative to H2 is between one and two orders of magnitude lower than that calculated by published ion-molecule models of dark-cloud chemistry, but is quite consistent with recent model revisions based on new reaction rates. Formic acid was not detected in the archetypical dark cloud TMC-1, and was tentatively detected in the region of massive star formation W51.