Irvine, William

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Professor Emeritus of Astronomy
Last Name
Irvine
First Name
William
Discipline
Cosmology, Relativity, and Gravity
External Galaxies
Other Astrophysics and Astronomy
Physical Processes
Stars, Interstellar Medium and the Galaxy
The Sun and the Solar System
Expertise
Introduction
At present, in 2014, my principal activity in astrochemistry and astrobiology is as an editor of the Encyclopedia of Astrobiology, published by Springer.
I began my research career in astronomy with a dissertation in cosmology, specifically on the growth of structure in the expanding universe. A result was what has been called the Layzer-Irvine, or the Cosmic Energy, equation. A post-doctoral position at the Leiden Observatory in the Netherlands subsequently led me into those aspects of planetary and atmospheric science dealing with the transmission and reflection of radiation by atmospheres and rough surfaces, including what has been called the Hapke-Irvine law or relation.
After the establishment of the Five College Radio Astronomy Observatory, particularly the 14-meter diameter millimeter-wave telescope at the University of Massachusetts Amherst, my research switched into two new areas: the chemistry of dense interstellar clouds and the physics and chemistry of comets. Dense interstellar clouds are the most massive objects in the universe consisting of material subject to the chemical bond. The composition and the processes determining this composition are thus of fundamental importance to our understanding of the universe. As the chemical composition affects the heating and cooling processes of the cloud, there is a tight evolutionary link between chemistry, cloud physics and evolution, and star formation.
Although by far the most abundant molecular species in these clouds is molecular hydrogen, the trace constituents exhibit a complex organic (carbon-based) chemistry. At the least demonstrating that organic chemistry is widespread in the universe, this composition raises the question of what role interstellar organics might have played in the origin of life on Earth or elsewhere --- thus, this research becomes a part of astrobiology. An aspect of these studies is the search for and identification of new interstellar molecules. My colleagues and I have played a role in the discovery of some 13 such new molecular species, involving collaborations with astronomers
at Nobeyama Radio Observatory in Japan and the Onsala Space Observatory in Sweden.
The same radio techniques at millimeter and submillimeter wavelengths used to study interstellar matter are also useful in observing comets, the least processed material surviving from the origin of the solar system. Observations of cometary organic molecules can give information on cometary physics and the relation of comets to interstellar material. Since comets were clearly a source of organic matter for the early Earth, studying the nature and links between the organic chemistry in interstellar clouds and in comets is an important aspect of astrobiology.
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Now showing 1 - 10 of 105
  • PublicationMetadata only
    Survey Observations Of C-c2h4o And Ch3cho Toward Massive Star-forming Regions
    (2001) Ikeda, M; Ohishi, M; Nummelin, A; Dickens, JE; Bergman, P; Hjalmarson, A; Irvine, William M.
    In order to clarify the formation mechanisms of ethylene oxide (cyclic-C2H4O, hereafter c-C2H4O) and its structural isomer acetaldehyde (CH3CHO), we carried out survey observations of these two molecules toward 20 massive star-forming regions and two dark clouds. CH3CHO and c-C2H4O were detected in 10 massive star-forming regions, and CH3CHO was also detected in five others. The column densities and the rotational temperatures were derived using the rotation diagram method. The column densities of these molecules were derived to be (0.1-3.3) × 1014 and (0.2-5.0) × 1014 cm-2 for c-C2H4O and CH3CHO, respectively. The fractional abundances with respect to H2 are X(c-C2H4O) = 4 × 10-11 to 6 × 10-10 and X(CH3CHO) = 7 × 10-12 to 3 × 10-9. We also detected several transitions of methanol (CH3OH), ethanol (C2H5OH), dimethyl ether [(CH3)2O], methyl formate (HCOOCH3), formic acid (HCOOH), vinyl cyanide (C2H3CN), and ethyl cyanide (C2H5CN). Comparing the abundances of the detected molecules with physical conditions of each source, we found that the abundances of most of the molecules except for c-C2H4O and CH3CHO increase along with the dust temperature of each source. On the other hand, the abundances of c-C2H4O and CH3CHO show little correlation with the dust temperature. The rotation temperatures of c-C2H4O, CH3CHO, and HCOOH are low (10-40 K) in all sources in spite of the fact that the gas kinetic temperature greatly varies from cloud to cloud. This may indicate that the line emission from each molecular species is excited in regions with different physical conditions. We performed pseudo-time-dependent chemical reaction simulations based on pure gas-phase reactions and found that the calculated abundances of observed molecules decreased when the gas kinetic temperature was raised. We investigated the relationship between the column density of C2H5OH and that of the C2H4O group (c-C2H4O + CH3CHO) because C2H5OH is believed to be a precursor of c-C2H4O and CH3CHO in the gas-phase chemistry scheme. If this hypothesis is correct, it is expected that the column density of C2H5OH is related to that of the C2H4O group. We found that the column density of the C2H4O group is high in sources where the column density of C2H5OH is high. This result is consistent with the above-mentioned hypothesis. We also investigated the relationships between the column densities of several organic species [CH3OH, C2H5OH, (CH3)2O, HCOOCH3, C2H3CN, and C2H5CN] and the luminosity-to-mass ratio, LIR/M, in OMC-1, W51A, and Sgr B2(N). We found that the column densities of these molecules are high in sources where LIR/M is high. Since LIR/M is believed to be a measure of the star formation rate per unit mass, it indicates that the column densities of these molecules become higher in sources where high star formation activity leads to a higher dust temperature. This strongly suggests that the formation of these molecules involves processes on the dust grains and subsequent sublimation to the gas phase, where they can be observed.
  • PublicationMetadata only
    H2cs Abundances And Ortho-to-para Ratios In Interstellar Clouds
    (1991) MINH, YC; Irvine, William M.; BREWER, MK
    Several H2CS ortho and para transitions have been observed toward interstellar molecular clouds, including cold, dark clouds and star-forming regions. H2CS fractional abundances f(H2CS) about 1-2 10 to the -9th relative to molecular hydrogen toward TMC-1, Orion A, and NGC 7538, and about 5 10 to the -10th for L134N are derived. The H2CS ortho-to-para ratios in TMC-1 are about 1.8 toward the cyanopolyyne peak and the ammonia peak, which may indicate the thermalization of H2CS on 10 K grains. A ratio of about 3, the statistical value, for Orion (3N, 1E) and NGC 7538 is derived, while a value of about 2 for Orion (KL) is found.
  • PublicationMetadata only
    Thermal History, Chemical-composition And Relationship Of Comets To The Origin Of Life
    (1980) Irvine, William M.; LESCHINE, SB; SCHLOERB, FP
    It is generally believed that a comet consists basically of a loose conglomeration of frozen gases with embedded material similar to that found in the carbonaceous chondritic meteorites, and consequently that comets may be nearly pristine samples of the original solar nebula1−5. We show here that thermal processing within comets could have played an important part in determining their present state; in particular, we find that liquid water might have been available in some comets over geologically and biologically significant spans of time. It follows that a cometary origin is not excluded for some thermally metamorphosed meteorites and asteroids, that comets may contain quite complex organic molecules, and that comets may have played a role in the origin and conceivably even in the subsequent evolution of terrestrial life.
  • PublicationMetadata only
    Abundances Of Hydrogen-sulfide In Star-forming Regions
    (1991) MINH, YC; ZIURYS, LM; Irvine, William M.; MCGONAGLE, D
    Interstellar H2S and its isotopic variant H2(S-34) have been observed toward several star-forming regions via their 1(10)-1(01) transitions at 2 mm, using the FCRAO telescope. In sources where both isotopic species were observed, column densities of about 10 to the 16th/sq cm were measured. Column density lower limits of about 10 to the 14th/sq cm for H2S were found for other sources, where only the main isotopic line was observed. The fractional abundances of H2S relative to molecular hydrogen appear to be enhanced by at least an order of magnitude relative to quiescent cloud values (about 10 to the -9th) for many of the observed sources.
  • PublicationMetadata only
    Observations Of H2s Toward Omc-1
    (1990) MINH, YC; ZIURYS, LM; Irvine, William M.; MCGONAGLE, D
    Observations of the 1(10) - 1(01) transition of interstellar H2S and its isotopes toward OMC-1 are reported. The fractional abundance of H2S in the quiescent regions of OMC-1 seems difficult to explain by currently known ion-molecular reactions. The fractional abundance of H2S relative to H2 is enhanced by a factor of 1000 in the hot core and the plateau relative to the quiescent clouds. The (HDS)/(H2S) abundance ratio in the hot core is estimated at 0.02 or less.
  • PublicationMetadata only
    Spectroscopic Evidence For Interstellar Ices In Comet Hyakutake
    (1996) Irvine, William M.; BockeleeMorvan, D; Lis, DC; Matthews, HE; Biver, N; Crovisier, J; Davies, JK; Dent, WRF; Gautier, D; Godfrey, PD; Keene, J; Lovell, AJ; Owen, TC; Phillips, TG; Rauer, H; Schloerb, FP; Senay, M; Young, K
    VOLATILE compounds in comets are the most pristine materials surviving from the time of formation of the Solar System, and thus potentially provide information about conditions that prevailed in the primitive solar nebula1–3. Moreover, comets may have supplied a substantial fraction of the volatiles on the terrestrial planets, perhaps including organic compounds that played a role in the origin of life on Earth4–6. Here we report the detection of hydrogen isocyanide (HNC) in comet Hyakutake. The abundance of HNC relative to hydrogen cyanide (HCN) is very similar to that observed in quiescent interstellar molecular clouds, and quite different from the equilibrium ratio expected in the outermost solar nebula, where comets are thought to form. Such a departure from equilibrium has long been considered a hallmark of gas-phase chemical processing in the interstellar medium7, suggesting that interstellar gases have been incorporated into the comet's nucleus, perhaps as ices frozen onto interstellar grains. If this interpretation is correct, our results should provide constraints on the temperature of the solar nebula, and the subsequent chemical processes that occurred in the region where comets formed.
  • PublicationMetadata only
    Upper Limits For The Ethyl-cyanide Abundances In Tmc-1 And L134n - Chemical Implications
    (1991) MINH, YC; Irvine, William M.
    We have sought interstellar ethyl-cyanide via its 202–101 transition towards two cold, dark clouds and report upper limits of the total column densities of 3×1012cm–2 and 2×1012cm–2 for TMC-1 and L134N, respectively. We also observed the 202–101 transition of vinyl cyanide previously identified in TMC-1 by Matthews and Sears (1983b). The detection of vinyl cyanide and the non-detection of ethyl cyanide in TMC-1 are consistent with gas phase ion-molecule chemical models, and there is thus no necessity of invoking grain surface synthesis for vinyl cyanide in cold clouds.
  • PublicationMetadata only
    Theoretical Interpretation Of The Ground-based Photometry Of Saturns B-ring
    (1983) LUMME, K; Irvine, William M.; ESPOSITO, LW
    New photographic photometry at small tilt angles during the 1979 and 1981 apparitions is combined with earlier data to yield several physical parameters for Saturn's B ring in red and blue colors. Phase curves are obtained for a mean tilt angle B 6°. The value of the volume density D is 0.020±0.004 with no indication of dependence on either the color or the tilt angle for 6°
  • PublicationMetadata only
    Studies Of Organic-molecules Containing Methyl-groups In Dark Clouds
    (1987) FRIBERG, P; Irvine, William M.; MADDEN, SC; HJALMARSON, A
  • PublicationMetadata only
    Observations Of Cumulene Carbenes, H2cccc And H2ccc, In Tmc-1
    (1991) KAWAGUCHI, K; KAIFU, N; OHISHI, M; ISHIKAWA, S; HIRAHARA, Y; YAMAMOTO, S; SAITO, S; TAKANO, S; MURAKAMI, A; VRTILEK, JM; GOTTLIEB, CA; THADDEUS, P; Irvine, William M.
    http://adsabs.harvard.edu/abs/1991PASJ...43..607K