Loading...
Thumbnail Image
Publication

Norbornadienes: Robust and Scalable Building Blocks for Cascade “Click” Coupling of High Molecular Weight Polymers

Abstract
Herein, we report the development of a scalable and synthetically robust building block based on norbornadiene (NBD) that can be broadly incorporated into a variety of macromolecular architectures using traditional living polymerization techniques. By taking advantage of a selective and rapid deprotection with tetrazine, highly reactive “masked” cyclopentadiene (Cp) functionalities can be introduced into synthetic polymers as chain-end groups in a quantitative and efficient manner. The orthogonality of this platform further enables a cascade “click” process where the “unmasked” Cp can rapidly react with dienophiles, such as maleimides, through a conventional Diels–Alder reaction. Coupling proceeds with quantitative conversions allowing high molecular weight star and dendritic block copolymers to be prepared in a single step under ambient conditions.
Type
article
article
Date
2019-01-01
Publisher
Degree
Advisors
Rights
License
Research Projects
Organizational Units
Journal Issue
Embargo
Publisher Version
Embedded videos
Collections