Publication Date
2018
Journal or Book Title
Science Advances
Abstract
Mesostructured matter composed of colloidal nanocrystals in solidified architectures abounds with broadly tunable catalytic, magnetic, optoelectronic, and energy storing properties. Less common are liquid-like assemblies of colloidal nanocrystals in a condensed phase, which may have different energy transduction behaviors owing to their dynamic character. Limiting investigations into dynamic colloidal nanocrystal architectures is the lack of schemes to control or redirect the tendency of the system to solidify. We show how to solidify and subsequently reconfigure colloidal nanocrystal assemblies dimensionally confined to a liquid-liquid interface. Our success in this regard hinged on the development of competitive chemistries anchoring or releasing the nanocrystals to or from the interface. With these chemistries, it was possible to control the kinetic trajectory between quasi–two-dimensional jammed (solid-like) and unjammed (liquid-like) states. In future schemes, it may be possible to leverage this control to direct the formation or destruction of explicit physical pathways for energy carriers to migrate in the system in response to an external field.
DOI
http://dx.doi.org/10.1126/sciadv.aap8045
Volume
4
Issue
8
License
UMass Amherst Open Access Policy
Creative Commons License
This work is licensed under a Creative Commons Attribution-Noncommercial 4.0 License
Recommended Citation
Zhang, Ziyi; Jiang, Yufeng; Huang, Caili; Chai, Yu; Goldfine, Elise; Liu, Feng; Feng, Wenqian; Forth, Joe; Williams, Teresa E.; Ashby, Paul D.; Russell, Thomas P.; and Helms, Brett A., "Guiding kinetic trajectories between jammed and unjammed states in 2D colloidal nanocrystal-polymer assemblies with zwitterionic ligands" (2018). Science Advances. 1150.
http://dx.doi.org/10.1126/sciadv.aap8045