Off-campus UMass Amherst users: To download dissertations, please use the following link to log into our proxy server with your UMass Amherst user name and password.
Non-UMass Amherst users, please click the view more button below to purchase a copy of this dissertation from Proquest.
(Some titles may also be available free of charge in our Open Access Dissertation Collection, so please check there first.)
The crystallization and morphology of polyethylene and its blends
Abstract
The techniques of neutron and x-ray scattering have been used to study the morphology and crystallization behavior of polyethylene and blends of polyethylene. Synchrotron radiation was used to study the crystallization behavior of blends of high density polyethylene/ low density polyethylene (HDPE/LDPE) and linear low density/ low density polyethylene (LLDPE/LDPE). Simultaneous real time small and wide angle scattering from blends slowly cooled at (0.5$\sp\circ$C/min) seem to indicate that the lamellae are formed in bundles of primarily one component. For blends quickly cooled from the melt (quenched to 60$\sp\circ$C) on the other hand, the lamellae are randomly mixed together. HDPE/LDPE and LLDPE/LDPE blends show qualitatively the same crystallization behavior throughout the composition range except for 10%/90% LLDPE/LDPE. At this composition, extensive cocrystallization may be occurring in even slowly cooled samples. Small angle neutron and x-ray scattering was used to determine the location of the short chain branches in selectively deuterated LLDPE. Specially prepared LLDPE with the main chain deuterated was used in these experiments to provide contrast for neutron scattering. Despite density contributions to the neutron scattering from crystalline and amorphous regions, differences between the x-ray and neutron scattering suggest that the concentration of branches may be enhanced at the crystal- amorphous boundary. The extent of this branch-rich region was estimated to be about 30A. Lastly, the chain orientation of ultra high molecular weight PE (UHMWPE) was examined by small angle neutron scattering. A circularly averaging technique was applied in order to avoid sample alignment problems. Between extension ratios of 12 and 60, hot drawn (125$\sp\circ$C) gel crystallized UHMWPE does not show appreciable change in the perpendicular radius of gyration. However, changes in the asymptotic behavior of the scattering intensity from I $\sim$ q$\sp{-1.56}$ at 12x to I $\sim$ q$\sp{-1.2}$ at 60x indicate a change in geometry toward more rod like segments in the higher drawn material.
Subject Area
Polymer chemistry
Recommended Citation
Satkowski, Michael Matthew, "The crystallization and morphology of polyethylene and its blends" (1990). Doctoral Dissertations Available from Proquest. AAI9022740.
https://scholarworks.umass.edu/dissertations/AAI9022740