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Date of Award
2-2013
Access Type
Campus Access
Document type
dissertation
Degree Name
Doctor of Philosophy (PhD)
Degree Program
Chemistry
First Advisor
Vincent M. Rotello
Second Advisor
Dhandapani Venkataraman
Third Advisor
Matthew A. Holden
Subject Categories
Chemistry | Nanoscience and Nanotechnology | Organic Chemistry
Abstract
Engineering nanostructures with complete control over the shape, composition, organization of the surface structures, and function remains a major challenge. In my work, I have fabricated nanostructures using functional polymer motifs and nanoparticles (NPs) via supramolecular and non-supramolecular interactions. In one of the approaches to generate nanostructures, I have integrated top-down approaches such as nanoimprint lithography, electron-beam lithography, and photolithography with the self-assembly (bottom-up) of NPs to provide nanostructures with tailored shape and function. In this strategy, I have developed a geometrically assisted orthogonal assembly of nanoparticles onto polymer features at precisely defined locations. This versatile NP functionalization method can be used to fabricate protein resistant patterned surfaces to provide essentially complete control over cellular alignment, making them promising biofunctional structures for cell patterning. In another approach, I have utilized self-assembly of dendrimers and NPs without preformed templates to generate nanostructures that can be used as chemoselective membranes for the separation of small and biomacromolecules.
DOI
https://doi.org/10.7275/2jxz-w238
Recommended Citation
Subramani, Chandramouleeswaran, "Engineering Functional Nanostructures for Materials and Biological Applications" (2013). Doctoral Dissertations 1896 - February 2014. 441.
https://doi.org/10.7275/2jxz-w238
https://scholarworks.umass.edu/dissertations_1/441